Note! This review was written for a previous version of this file!
Excellent guide! A side-note, this technique should work for any program with 32-bit drivers.
One word of WARNING for ADVANCED USERS -- "XP Mode" is incompatible with other virtual machine (VM) applications including - but not limited to - VMWare, VirtualBox, etc. In fact, XP Mode is actually a dumbed-down virtual machine with XP preinstalled. Both XP Mode and another VM can be installed but running both at the same time will result in a Blue Screen of Death on the physical "host" computer.
If you need/want to use VMWare, VirtualBox, etc. your best bet is to load your own 32-bit operating system (XP, Vista, or Windows 7) and use TI-Connect (or whatever) within that.